chemistry Important Questions

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Chemistry Test 3×10, 5×3. Maximum time: 75minutes

  1. Define a. Orbital b. Node c. Sideways overlapping d. Hyperconjugation e. olefins f. Rotamers
  2. Draw boundary surface diagram of d-orbitals and p-orbitals.
  3. a. compare covalent radius and vander waal radius. b. Compare inter and intra hydrogen bond
  4. Draw Lewis structure of CO2 and O3 and find forma charge on each atom.
  5. Define dipole moment. Write some postulates of Fajans rule.
  6. Write E.C and write number of unpaired electrons a. Ni2+ b. Fe2+ c. Cu+.
  7. Explain a. Heigenberg uncertainty principle b. Pauli exclusion principle c. Hund rule of maximum multiplicity.
  8. Explain the mechanism of free radical substitution reaction.
  9. Write IUPAC name of the following: a. CH3(CH2)2(OH)CH2CH2CHO b. CH3NHCH3 c. CH3CH2CH2COBr write molecular formula of the following a. O-xylene b. Ethyl propanoate c. C6H5(OMe)
  10. Derive relation between Kc and Kp. Find Ph of solution which is mixture of 10ml of .2M H2SO4 and 20 ml of .1M HCl.
  11. Write effect of reactant, pressure and catalyst on equilibrium. Define buffer solution write it’s examples. Define molar solubility.
  12. a. Find radius and energy of 2nd orbit of Li2+ ion. b. Find kinetic energy of electron whose wave length is 4500 angstrom. c. Find ionization energy of He+ ion to give He2+. d. If Ksp of reaction A2B(s)+H2O—–>2A+ + B- is 8×10^-6. Find molar solubility.
  13. a. Draw Newman projection of ethane b. Compare dipole moment of NH3 and NF3 c. Draw hybrid orbitals of Ethene d. Find all quantum number of last electron of 4d^7. e. Find hybridization of PCl5.
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